Dune
Paul Atreides arrives on the desert planet Arrakis — the only source of the spice melange, the most valuable substance in the universe — and becomes entangled in ecological, political, and religious forces beyond any single person's control. Herbert's novel is the most influential SF book ever written: its world-building (the ecology of Arrakis, the Bene Gesserit sisterhood, the spice economy) established templates for the genre that are still being used sixty years later. Star Wars, Game of Thrones, Avatar, and countless other works are direct descendants. The first of a six-novel series; only the original stands alone.
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